I have a situation, new semi-gloss latex paint is peeling by the sheets off of newly primed walls. The thing is, I used a flat ceiling paint as a primer which I have done many times before, and a standard latex semi-gloss over it and it is peeling off in sheets! Help
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How long did the paint dry before peeling and how did it first happen? Your right that there shouldn't be any problems. I have used a flat first coat many times without problems.
First stop peeling the paint, I assume you are picking at it. It does take time for a semi-gloss to cure and get fully adhered to the surface. Maybe your paint needs more time to cure. What brand are you using?